Synthesis, Crystal Structure and Antimicrobial Properties of 1-Diphenylmethylpiperazine-1,4-Diium Tetrachloridocuprate

  • Sonia Mokaddem
  • Hadda-Imene Ouzari
  • Nedra Korbi
  • Habib Boughzala IPEIN
Keywords: Crystal structure, DRX, copper, 1-diphenylmethylpiperazine, hybrid material, infrared spectroscopy, antimicrobial activity, RDA

Abstract

New organic/inorganic hybrid (C17H22N2)[CuCl4] was elaborated and studied by single crystal X-ray diffraction. The compound crystallizes in the orthorhombic Pbca space group. The isolated [CuCl4]2- tetrahedra are slightly distorted building a 0-D anionic framework. The double protonation of the organic cation establish N—H···Cl interactions between organic and inorganic moieties leading to self-organized structure. Infrared, UV-Visible and photoluminescence studies were carried out. The in-vitro antibacterial and antifungal activity of the title salt against several microorganisms were studied. The purity of the material was controlled by Rietveld analysis based on structural investigations and X-ray powder diffraction.

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Published
2018-12-30
How to Cite
Mokaddem, S., Ouzari, H.-I., Korbi, N., & Boughzala, H. (2018). Synthesis, Crystal Structure and Antimicrobial Properties of 1-Diphenylmethylpiperazine-1,4-Diium Tetrachloridocuprate. To Chemistry Journal, 1(3), 300-312. Retrieved from http://purkh.com/index.php/tochem/article/view/181
Section
Research Articles