Structural Effects of Silicon Substitution on Hydroxyapatite Structure with High Substitution Ratio By Rietveld’s Analysis
The silicon-substituted hydroxyapatite (Si-HA) with three different Si-substitution levels were synthesized via aaqueous precipitation method, in the absence of any surfactants and organic solvents. The composition of the Si-substituted HA phases and effect of silicon substitution on the crystal structurewere investigated by Rietveld refinements from powder X-ray diffraction data. The results show that the final compounds are oxy-hydroxyapatites, a chemical formula for the Si-substituted HA phases with indication of the incorporated silicate amount is proposed.
Suchanek W, Yoshimura M. J Mater Res 1998;13:94–117.
H. Yuan, H Fernandes, P. Habibovic, J.D. Boer, A.M.C. Barradas, A.D. Ruiter, W.R. Walsh, C.A.V. Blitterswijk, J.D.D. Bruijn, Proc. Natl. Acad. Sci. USA 107 (31) (2010) 13614–13619.
L. Xia, K. Lin, X. Jiang, Y. Xu, M. Zhang, J. Chang, Z. Zhang, J. Mater. Chem. B 1 (40) (2013) 5403–5416.
Q. Zhai, S. Zhao, X. Wang, X. Li, W. Li, Y. Zheng, J. Inorg. Mater. 28 (1) (2013) 58–62.
K. Guth, C. Campion, T. Buckland, K.A. Hing, J. Mater. Sci.: Mater. Med. 22 (10) (2011) 2155–2164.
A. Aminian, M. Solati-Hashjin, A. Samadikuchaksaraei, F. Bakhshi, F. Gorjipour, A. Farzadi, F. Moztarzadeh, M. Schmücker, Ceram. Int. 37 (4) (2011) 1219–1229.
I. R. Gibson, J. Huang, S. M. Best, and W. Bonfield, Bio ceramics 12 (1999) 191.
N. Patel, S. M. Best, W. Bonfield, I. R. Gibson, K. A. Hing, E. Damien, and P. A. Revell, J. Mater. Sci.-Mater. Med. 13 (2002) 1199.
I. R. Gibson, S. M. Best, and W. Bonfield, J. Biomed. Mater. Res. 44 (1999) 422.
D. Arcos, J. Rodriguez-Carvajal, M. Vallet-Regi, Chem. Mater. 16 (2004) 2300.
B. Chafik El Idrissi, K. Yamni, A. EL Yacoubi, A. Massit, IOSR Journal of Applied Chemistry, 2278 5736. Volume 7, Issue 5 Ver. III, pp. 107-112, May-2014.
A. El Yacoubi, A. Massit, M. Fathi, B. Chafik El Idrissi, K. Yamni, J. App. Chemistry 7(11), 24–29 (2014).
M.I. Kay, R.A. Young, A.S. Posner, Nature 204 (1964) 1050.
P. Thompson, D. E. Cox, J.B. Hastings, J. Appl. Crystallogr. 20, p. 79, 1987
I.R. Gibson, S.M. Best, W. Bonfield, J. Amer. Ceram. Soc. 85 (11) (2002) 2771.
A. El Yacoubi, A. Massit, S. El Moutaoikel, A. Rezzouk, B. Chafik El Idrissi ,American Journal of Materials Science and Engineering. 2017, 5(1), 1-5.
Copyright (c) 2018 To Chemistry Journal
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors retain the copyright of their manuscripts, and all Open Access articles are distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided that the original work is properly cited.
To Chemistry Journal allow the author(s) to retain publishing rights without restrictions.