Effect of Oxidant 1, 3-Dichloro-5-5-Dimethylhydantoin and 5, 5-Dimethylhydantoin with Different Substrates: The Kinetic Measurements

  • Dr Arvind Prasad Dwivedi
  • Shweta Neeraj
  • S. S. Parihar
Keywords: Kinetic measurement, concentration, catalytic effect, hydrolysis, reveal

Abstract

The kinetic measurement with different concentration of oxidant 1,3-dichloro-5,5-dimethylhydantoin and 5,5-dimethylhydantoin with ℓ–alanine,  ℓ-glycine and ℓ–valine. The catalytic effect of acid in the reaction rate reveal an interaction between oxidants species H2O+Cl and substrates. The observed order of reactivity of ℓ-amino acids (ℓ-glycine > ℓ–alanine > ℓ-valine) was explained on the basis of hydrolysis of reacting species.

Downloads

Download data is not yet available.

Author Biographies

Dr Arvind Prasad Dwivedi

Department of Chemistry, Govt. Sanjay Gandhi Smrati Auto., P.G., College Sidhi M.P

Shweta Neeraj

Department of Chemistry, Govt. Girls P.G. College (NAAC) Rewa-486001 (M.P.) India

S. S. Parihar

Department of Chemistry, Govt. Girls P.G. College (NAAC) Rewa-486001 (M.P.) India

References

Xu ZJ, Zhang Dy, Zou XZ, Synth commu 2006, 36, 255-258.

Spitulnik MJ. : Synthesis 1985, 299-300.

Shapiro EL, Centles MJ, Tiberi RL, Popper TL, Berkenkopf J, Lutsky B, Watnick AS. : J Med Chem 1987, 30, 1581-1588.

Karmazin L, Mazzanti M, Bezombes JP, Gateau C, Pecaut J, Inorg Chem 2004, 43, 5147-5158.

Barnes DM, Christesen AC, Engstrom KM, Haight AR, Stoner EJ, Wagaw S, Org process Res Dev 2006, 10, 803-807.

Chen BC, Murphy CK, Kumar A, Clark C, Zhou P, Lewis BM, Buckley J. : Organic synthesis 1996, 73, 159-173.

Mergelsberg I, Gala D, Scherer D, Dibenedetto D, Tanner M. : Tetrahedron Lett 1992, 33, 161-164.

Miesch L, Gateau C, Morin F, Franck-Neumaann M, Tetrahedron Lett. 2002, 43, 7635-7638.

Szumigala RH, Devine PN, Gautheir DR, Volante RP, J Org Chem 2004, 69, 566-569.

Zolifigol MA, Nasr-Isfahani H, Mallakpour S, Safaiee M, Synlett 2005, 761-764.

Khazaei A, Manesh AA, Synthesis 2005, 1929-1931.

Shakya PD, Dubey DK, Pardasani D, Palit M, Gupta AK, Org Prep Proced Int 2005, 37, 569-574.

Barta NS, Sidler DR, Somerville KB, Weissman SA, Larsen RD, Reider PJ. : Org Lett 2000, 2, 2821-2824.

Harding M, BGodkin JA, Hutton CA, Synlett 2005, 2829-2831.

Zolfigol MA, Ghaemi E, Madrakian E, Choghamarani AG, Mendeleev commun 2006, 41-42.

Nikman K, Zolfigol MA. L J Iran Chem Soc 2006, 3, 59-63.

DiBlasi CM, Macks DE, Tan DS,Org Lett 2005, 7, 1777-1780.

Grela K, Tryznowski M, Bieniek M., Tetrahedra Lett 2002, 43, 9055-9059.

Neeraj Shweta, Parihar SS, Dwivedi AP, Int J Adv Research in Chemical Science (IJARCS) 2018, 4, 9-14.

Neeraj Shweta, Parihar SS, Dwivedi AP, Int J Adv Research in Chemical Science (IJARCS) 2018, 5, 25-30.

Neeraj Shweta, Parihar SS, Dwivedi AP, Int J Adv Research in Chemical Science (IJARCS) 2018, 5, 1-5.

Neeraj Shweta, Parihar SS, Dwivedi AP, Int J Engineering and Information Systems (IJEAIS) 2018, 2, 27-31.

Published
2018-12-30
How to Cite
Dwivedi, D. A. P., Neeraj, S., & S. Parihar, S. (2018). Effect of Oxidant 1, 3-Dichloro-5-5-Dimethylhydantoin and 5, 5-Dimethylhydantoin with Different Substrates: The Kinetic Measurements. To Chemistry Journal, 1(3), 386-391. Retrieved from http://purkh.com/index.php/tochem/article/view/235
Section
Research Articles