Characterization and Compositional Analysis of Indian Black Aggregate as a Concrete Raw Material

  • Md. Zaved Hossain Khan Jessore University of Science and Technology
Keywords: Black aggregates, Physiochemical properties, Surface morphology, Minerals


The study is conducted to find the applicability of Indian black aggregate as a concrete material through a series of physiochemical and surface morphological investigation. The report reveals the effects of different chemical properties on concrete performance which ultimately affect life period of any structure. Mineralogical and Chemical characterization of the aggregate was analysed by UV visible spectroscopy (UV-vis), X-Ray Fluorescence (ED-XRF) and X-Ray Diffraction (XRD). Scanning electron microscopy (SEM) used to know Surface morphology of the aggregate. It was observed that studied aggregate contains high amount of MgO (4.36%) and Fe2O3 (14.84%). However, it is quite stable up to 800 oC with loss of only 1.58% of gross weight. The surface morphology analysis clearly revealed the existence of Calcite, Quartz and Dolomite materials in studied aggregate.


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1. Meyer C. The greening of the concrete industry. Cem Concr Compos 2009;31(8):601–5.
2. Zivica V, Bajza A. Acidic attack of cement based materials - a review. Part 1. Principle of acidic attack. Construct Build Mat 2000; 15:331-40.
3. Collepardi M. Simplified modelling of calcium leaching of concrete in various environments. Mat Struct Mat Const 2002;3:633-40.
4. Beddoe RE, Dorner HW. Modelling acid attack on concrete: Part I. The essential mechanism. Cement Concrete Res 2005;35:2333-39.
5. Vollertsen J, Nielsen AH, Jensen HS, Andersen TW, Jacobsen TH. Corrosion of concrete sewers—The kinetics of hydrogen sulfide oxidation, Sci Envi 2008;394:162-170.
6. Josée Duchesne and Benoît Fournier, Deterioration of Concrete by the Oxidation of Sulphide Minerals in the Aggregate, Journal of Civil Engineering and Architecture, Aug. 2013, Volume 7, No. 8 (Serial No. 69), pp. 922-931 ISSN 1934-7359, USA
7. J.P.R. de Villiers, D.C. Liles, The crystal-structure and vacancy distribution in 6C pyrrhotite, American Mineralogist 95 (2010) 148-152.
8. D.C. Liles, J.P.R. de Villiers, Redetermination of the structure of 5C pyrrhotite at low temperature and at room temperature, American Mineralogist 97 (2012) 257-261.
9. M. Becker, J. de Villiers, D. Bradshaw, The mineralogy and crystallography of pyrrhotite from selected nickel and PGE ore deposits, Economic Geology 105 (2010) 1025-1037.
10. I. Casanova, L. Agullo, A. Aguado, Aggregate expansivity due to sulphide oxidation—I. Reaction system and rate model, Cement and Concrete Research 26 (1996) 993-998.
11. J. Berard, R. Roux, M. Durand, Performance of concrete containing a variety of black shale, Canadian Journal of Civil Engineering 2 (1975) 58-65.
12. . S. Chinchon, C. Ayora, A. Aguado, F. Guirado, Influence of weathering of iron sulfides contained in aggregates on concrete durability, Cement and Concrete Research 25 (1995) 1264-1272.
13. [13] C. Ayora, S. Chinchon, A. Aguado, F. Guirada, Weathering of iron sulfides and concrete alteration, Cement and Concrete Research 28 (4) (1998) 1223-1235.
14. Braga M, de Brito J, Veiga R. Incorporation of fine concrete aggregates in mortars. Constr Build Mater 2012;36:960–8.
15. Smith BJ, Roberts LR, Funkhouser GP, Gupta V, Chmelka BF. Reactions and surface interactions of saccharides in cement slurries. Langmuir 2012;28:14202–17.
16. Pereira P, Evangelista L, de Brito J. The effect of superplasticisers on the workability and compressive strength of concrete made with fine recycled concrete aggregates. Constr Build Mater 2012;28:722–9.
17. T.Y. Lo, W.C. Tang, H.Z. Cui. The effect of aggregate absorption on pore area at interfacial zone of lightweight concrete, Construction and Building Materials, 2008, 22, 623-628.
18. T. Y. Lo, H.Z. Cui, W.C. Tang, W.M. Leung. The effects of aggregate properties on lightweight concrete, Building and Environment, 2007, 42, 3025–3029.
19. D. Fragoulis, M.G. Stamatakis, E. Chaniotakis, G. Columbus. Characterization of lightweight aggregates produced with clayey diatomite rocks originating from Greece, Materials Characterization, 2004, 53, 307– 316.
20. İ.B. Topçu, T.U. Lu. Effect of aggregate type on properties of hardened self-consolidating lightweight concrete (SCLC), Construction and Building Materials, 2010, 24, 1286-1295.
21. B. Ruggero, S. Filippozzi, E. Princi, C. Schenone, S. Vicini, Acoustic and mechanical properties of expanded clay granulate consolidated by epoxy resin, Applied Clay Science, 2010,48, 460–465.
22. Shih-Wei Cho. Effect of Silt Fines on the Durability Properties of Concrete. Journal of Applied Science and Engineering, Vol. 16, No. 4, pp. 425-430 (2013).
23. Lerch, William, 1955, Chemical reaction of concrete aggregate: American Society for Testing and Materials Special Technical Publication 169, p. 334- 345.
24. F. Okonta, A. Derrick The Effect of Iron Oxide on the Strength of Soil/Concrete Interface, Proceedings of the 15th African Regional Conference on Soil Mechanics and Geotechnical Engineering, P. 355 – 359 DOI10.3233/978-1-60750-778-9-355
25. Neville, A. M., 1973, Properties of concrete: New York, NY, John Wiley and Sons, 686 p.
How to Cite
Khan, M. Z. (2019). Characterization and Compositional Analysis of Indian Black Aggregate as a Concrete Raw Material. To Chemistry Journal, 2, 51-59. Retrieved from
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