Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction

  • Milivoj Lovrić Šebojka doo
  • Šebojka Komorsky-Lovrić
Keywords: ECE Mechanism, Square Wave Voltammetry, Theory, Kinetics, Equilibrium Conditions

Abstract

A theory of the mechanism that consists of two reversible electrode reactions coupled by kinetically controlled reversible chemical reaction is developed for square wave voltammetry on stationary planar electrode. The influences of frequency and the concentration of electro-inactive chemical reactant on the responses are investigated for thermodynamically stable intermediate. The limits of three types of responses are calculated and the formula for the estimation of the forward rate constant of chemical reaction is proposed.

Downloads

Download data is not yet available.

Author Biography

Šebojka Komorsky-Lovrić

Divkovićeva 13, Zagreb 10090, Croatia

References

Laviron, E.; Meunier-Prest, R.; J. Electroanal. Chem., 1992, 324, 1-18.

Molina, A.; Laborda, E.; Gomez-Gil, J. M.; Compton, R. G.; J. Solid State Electrochem., 2016, 20, 3239-3253.

Laborda, E.; Gomez-Gil, J. M.; Molina, A.; Phys. Chem. Chem. Phys. 2017, 19, 16464–16476.

Lin, Q.; Li, Q.; Batchelor-McAuley, C.; Compton, R. G.; J. Phys. Chem. C, 2015, 119, 1489–1495.

Gulaboski, R.; Markovski, V.; Jihe, Z.; J. Solid State Electrochem., 2016, 20, 3229-3238.

Molina, A.; Laborda, E.; Gomez-Gil, J. M.; Martinez-Ortiz, F.; Compton, R. G.; Electrochim. Acta, 2016, 195, 230–245.

Feldberg, S. W.; J. Phys. Chem., 1971, 75, 2377-2380.

Amatore, C.; Saveant, J. M.; J. Electroanal. Chem., 1978, 86, 227-232.

Palys, M. J.; Bos, M.; van der Linden, W. E.; Anal. Chim. Acta, 1993, 283, 811-829.

Sanecki, P. T.; Amatore, C.; Skital, P. M.; J. Electroanal. Chem., 2003, 546, 109-121.

Sanecki, P. T.; Skital, P. M.; Electrochim. Acta, 2008, 53, 7711-7719.

Gulaboski, R.; Mirčeski, V.; Bogeski, I.; Hoth, M.; J. Solid State Electrochem., 2012, 16, 2315-2328.

Engblom, S. O.; Myland, J. C.; Oldham, K. B.; Anal. Chem., 1994, 66, 3182.

Galvez, J.; Molina, A.; Saura, R.; Martinez, F.; J. Electroanal. Chem., 1981, 127, 17.

Amatore, C.; Saveant, J. M.; J. Electroanal. Chem., 1977, 85, 27.

Mann, M. A.; Helfrick Jr., J. C.; Bottomley, L. A.; J. Electrochem. Soc., 2016, 163, H3101-H3109.

Miles, A. B.; Compton, R. G.; J. Electroanal. Chem., 2001, 499, 1-16.

O'Dea, J. J.; Wikiel, K.; Osteryoung, J.; J. Phys. Chem., 1990, 94, 3628-3636.

Miles, A. B.; Compton, R. G.; J. Phys. Chem. B, 2000, 104, 5331-5342.

Komorsky-Lovrić, Š.; Lovrić, M.; Anal. Bioanal. Electrochem., 2013, 5, 291-304.

Lovrić, M.; J. Electrochem. Sci. Eng., 2017, 7, 119-129.

Olmstead, M. L.; Nicholson, R. S.; J. Electroanal. Chem., 1968, 16, 145-151.

Bieniasz, L. K.; Modelling Electroanalytical Experiments by the Integral Equation Method, Springer, Berlin, 2015.

Komorsky-Lovrić, Š.; Lovrić, M.; Croat. Chem. Acta, 2017, 90, 27-35.

Published
2019-04-30
How to Cite
Lovrić, M., & Komorsky-Lovrić, Šebojka. (2019). Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction. To Chemistry Journal, 2, 142-153. Retrieved from http://purkh.com/index.php/tochem/article/view/350
Section
Research Articles