Preparation of Ferromagnetic Co3O4 Nanoparticles by Wet Chemical Synthesis Method

  • Majid Farahmandjou Islamic Azad University
Keywords: Co3O4 nanoparticles, wet chemical, crystal properties, synthesis

Abstract

Cobalt oxide nanoparticles (Co3O4) were synthesized by wet chemical method using cobalt sulfate as precursor and ethylene glycol as surfactant. Their physico-chemical properties were characterized by high resolution transmission electron microscopy (HRTEM), field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) and vibration sampling magnetometer (VSM) analyses. The crystal structure of samples after annealing was done by XRD analysis. XRD measurement exhibited the structure of Co3O4 nanocrystals for annealed samples.  The TEM results showed the cobalt oxide nanoparticles with good uniformity. The SEM images revealed that the size of nanoparicles increased in the range of 20-50 nm with increasing annealing temperature. The magnetic results indicated a good coercive field and saturation magnetism around 452 G and 18 emu/g, respectively.                                                                                  

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Author Biography

Majid Farahmandjou, Islamic Azad University

Department of Chemistry, Faculty of Pharmaceutical Sciences, Tehran Medical Sciences, Islamic Azad University, Tehran, Iran

References

Jurablu, S.; Farahmandjou, M.; Firoozabadi, T. P., Multiple-layered structure of obelisk-shaped crystalline nano-ZnO prepared by sol–gel route. J. Theoretical. Appl. Phys. 2015, 9, 261–266. DOI: 10.1007/s40094-015-0184-6.

Zarinkamar, M.; Farahmandjou, M.; Firoozabadi, T. P., Diethylene Glycol-Mediated Synthesis of Nano-Sized Ceria (CeO2) Catalyst. J. Nanostruct. 2016, 6, 114-118, DOI: 10.7508/jns.2016.02.002.

Farahmandjou, M.; Khalili, P., Morphology Study of anatase nano-TiO2 for Self-cleaning Coating. Int. J. Fund. Phys. Sci. 2013, 3, 54-56, DOI: 10.14331/ijfps.2013.330055.

M.; Ramazani, Farahmandjou, M., Firoozabadi, T.P, “Fabrication and Characterization of Rutile TiO2 Nanocrystals by Water Soluble Precursor”, Phys. Chem. Res. 2015, 3, 293-298, DOI: 10.22036/pcr.2015.10641.

M Farahmandjou, N Golabiyan, “Solution combustion preparation of nano-Al2O3: synthesis and characterization”, Transp. Phenom. Nano. Micro. Scales., 3 (2015) 100-105.

Farahmandjou, M., Synthesis of ITO Nanoparticles Prepared by Degradation of Sulfide Method. Chin. Phys. Lett. 2012, 29, 077306-077309, DOI: 10.1088/0256-307X/29/7/077306.

Farahmandjou, M.; Golabiyan, N., Synthesis and characterization of Alumina (Al2O3) nanoparticles prepared by simple sol-gel method. Int. J. Bio-Inorg. Hybr. Nanomater. 2016, 5, 73-77.

Akhtari, F.; Zorriasatein, S.; Farahmandjou, M.; Elahi, S. M., Structural, optical, thermoelectrical, and magnetic study of Zn1-xCoxO (0 ≤ x ≤ 0.10) nanocrystals. Int. J. Appl. Ceram. Technol. 2018, 15, 723-733. DOI: 10.1111/ ijac.12848.

Akhtari, F.; Zorriasatein, S.; Farahmandjou, M.; Elahi, S. M., Synthesis and optical properties of Co2+-doped ZnO Network prepared by new precursors. Mater. Res. Express. 2018, 5, 065015-065024, DOI:10.1088/2053-1591/aac6f1.

Khoshnevisan, B.; Marami, M. B.; Farahmandjou, M., Fe3+-Doped Anatase TiO2 Study Prepared by New Sol-Gel Precursors. Chin. Phys. Lett. 2018, 35, 027501-027505. DOI:10.1088/0256-307X/35/2/027501.

Khoshnevisan, B.; Marami, M. B.; Farahmandjou, M., Solgel Synthesis of Fe-doped TiO2 Nanocrystals. J. electron. Mater. 2018, 47, 3741-3749. DOI: 10.1007/s11664-018-6234-5.

Jafari, A.; Khademi, S.; Farahmandjou, M., Nano-crystalline Ce-doped TiO2 Powders: Sol-gel Synthesis and Optoelectronic Properties. Mater. Res. Express. 2018, 5, 095008, DOI:10.1088/2053-1591/aad5b5.

Farahmandjou, M.; Khalili, P., Study of Nano SiO2/TiO2 Superhydrophobic Self-Cleaning Surface Produced by Sol-Gel. Aust. J. Basic. Appl. Sci. 2013, 7, 462-465.

Jurablu, S.; Farahmandjou, M.; Firoozabadi, T. P., Sol-gel synthesis of zinc oxide (ZnO) nanoparticles: study of structural and optical properties. J. Sci. Islamic Republic of Iran. 2015, 26, 281-285.

Farahmandjou, M.; Dastpak, M., Fe-Loaded CeO2 Nanosized Prepared by Simple Co-Precipitation Route. Phys. Chem. Res. 2018, 6, 713-720. DOI: 10.22036/pcr.2018.132220.1486.

Farahamndjou, M., The study of electro-optical properties of nanocomposite ITO thin films prepared by e-beam evaporation. Rev. mex. Fís. 2013, 59, 205-207.

Dastpak, M.; Farahmandjou, M.; Firoozabadi, T. P., Synthesis and preparation of magnetic Fe-doped CeO2 nanoparticles prepared by simple sol-gel method. J. Supercond Nov. Magn. 2016, 29, 2925-2929. DOI: 10.1007/s10948-016-3639-3.

S Motaghi and M Farahmandjou, “Structural and optoelectronic properties of Ce-Al2O3 nanoparticles prepared by sol-gel precursors”, Material Research Express 6 (4), (2019) 045008. Doi: 10.1088/2053-1591/aaf927

M. Zarinkamar, M. Farahmandjou, T.P. Firoozabadi, “One-step synthesis of ceria (CeO2) nano-spheres by a simple wet chemical method”, J. Ceram. Proc, Res. 17 (2016) 166-169.

S. Motaghi, M. Farahmandjou, “Structural and optoelectronic properties of Ce–Al2O3 nanoparticles prepared by sol-gel precursors”, Mater. Res. Express, 6 (2019) 045008, https://doi.org/10.1088/2053-1591/aaf927.

S. Behrouzinia, D. Salehinia; K. Khorasani; M. Farahmandjou, “The continuous control of output power of a CuBr laser by a pulsed external magnetic fiel” Optics Communications, 436 (2019) 143-145,https://doi.org/10.1016/j.optcom.2018.12.016.

M. Farahmandjou, S. Motaghi, “Sol-gel Synthesis of Ce-doped α-Al2O3: Study of Crystal and Optoelectronic Properties”, Optics Communications, 441 (2019) 1–7, https://doi.org/10.1016/j.optcom.2019.02.029.

A. Jafari, S. Khademi, M. Farahmandjou, A. Darudi, R. Rasuli, “Structural and optical properties of Ce3+-doped TiO2 nanocrystals prepared by sol-gel precursors”, Journal of Electronic Materials, 2018, 47(11), 6901–6908, https://doi.org/10.1007/s11664-018-6590-1.

A. Khodadadi, M. Farahmandjou and Mojtaba Yaghoubi, “Investigation on synthesis and characterization of Fe-doped Al2O3 nanocrystals by new sol–gel precursors”, Mater. Res. Express 6 (2019) 025029. https://doi.org/10.1088/2053-1591/aaef70

A. Khodadadi, M. Farahmandjou, M. Yaghoubi, “Investigation on synthesis and characterization of Fe-doped Al2O3 nanocrystals by new sol–gel precursors”, Mater. Res. Express 6 (2019) 025029, https://doi.org/10.1088/2053-1591/aaef70.

B. Khoshnevisan, M. B. Marami, M. Farahmandjou, “Fe3+-Doped Anatase TiO2 Study Prepared by New Sol-Gel Precursors”, Chin. Phys. Lett. 35 (2018) 027501-027505, https://doi.org/10.1088/0256-307X/35/2/027501.

M. B. Marami, M. Farahmandjou, B. Khoshnevisan, “Solgel Synthesis of Fe-doped TiO2 Nanocrystals” J. electron. Mater, 47(7) (2018) 3741–3748, https://doi.org/10.1007/s11664-018-6234-5.

Farahmandjou, M.; Soflaee, F., Polymer-Mediated Synthesis of Iron Oxide (Fe2O3) Nanorods. Chin. J. Phys. 2015, 53, 080801-080809. DOI: 10.6122/CJP.20150413.

Farahmandjou, M.; Soflaee, F., Synthesis and characterization of α-Fe2O3 nanoparticles by simple co-precipitation method. Phys. Chem. Res. 2015, 3, 193-198, DOI: 10.22036/pcr.2015.9193.

Farahmandjou, M., Magnetocrystalline properties of Iron-Platinum (L10-FePt) nanoparticles through phase transition. Iran. J. Phys. Res. 2016, 16, 1-5, DOI: 10.18869/acadpub.ijpr.16.1.1.

Shadrokh, S.; Farahmandjou, M.; Firozabadi, T. P., Fabrication and Characterization of Nanoporous Co Oxide (Co3O4) Prepared by Simple Sol-gel Synthesis. Phys. Chem. Res. 2016, 4, 153-160, DOI: 10.22036/pcr.2016.12909.

Farahmandjou, M.; Honarbakhsha, S.; Behrouziniab, S., PVP-Assisted Synthesis of Cobalt Ferrite (CoFe2O4) Nanorods. Phys. Chem. Res. 2016, 4, 655-662, DOI: 10.22036/pcr.2016.16702.

Farahmandjou, M., Synthesis and Structural Study of L10- FePt nanoparticles. Turk. J. Engin. Environ. Sci. 2010, 34, 265-270. DOI: 10.3906/muh-1010-20.

Farahmandjou, M.; Honarbakhsh, S.; Behrouzinia, S., FeCo Nanorods Preparation Using New Chemical Synthesis. J. Supercond. Nov. Magn., 31(12) 2018, 4147–4152, Doi: 10.1007/s10948-018-4659-y.

M. Farahmandjou, “Effect of oleic acid and oleylamine surfactants on the size of FePt nanoparticles”, J. supercond. Nov. magn. 25 (2012) 2075-2079, doi: 10.1007/s10948-012-1586-1.

S.A. Sebt, SS Parhizgar, M. Farahmandjou, P. Aberomand, M. Akhavan, “The role of ligands in the synthesis of FePt nanoparticles, “Journal of superconductivity and novel magnetism 22 (2009) 849, https://doi.org/10.1007/s10948-009-0509-2.

Y. W. Jun, J. H. Lee, J. “Chemical design of nanoparticle probes for high-performance magnetic resonance imaging”, Cheon, Angew Chem Int Ed. 47, 5122 (2008)., DOI:10.1002/anie.200701674

B. Gleich, J. Weizenecker, “Tomographic imaging using the nonlinear response of magnetic particles”, Nature. 435, 1214 (2005). DOI:10.1038/nature03808

D. P. Dinega, M. G. Bawendi,” A Solution-Phase Chemical Approach to a New Crystal Structure of Cobalt”, Angew. Chem. Int. Ed. 38, 1788 (1999). DOI:10.1002/(SICI)1521-3773(19990614)38:12<1788::AID-ANIE1788>3.0.CO;2-2

K. M. Krishnan, A. P. Alivisatos, “Colloidal nanocrystal shape and size control: the case of cobalt”, Science. 291, 2115 (2001). DOI:10.1126/science.1057553

T Hyeon, “Chemical synthesis of magnetic nanoparticles”, Chem. Commun. 8, 927 (2003). DOI: 10.1039/B207789B

S. Sun, C. B. Murray, “Synthesis of monodisperse cobalt nanocrystals and their assembly into magnetic superlattices”, J.Appl. Phys. 85, 4325 (1999). https://doi.org/10.1063/1.370357

R.H. Kodama, “Magnetic Nanoparticles”, J. Magn Magn Mater, 200, 359-372 (1999). https://doi.org/10.1016/S0304-8853(99)00347-9

M. Rutnakornpituk, M. Thompson, L. Harris, K. Farmer, A. Esker, J. Riffle, “Formation of cobalt nanoparticle dispersions in the presence of polysiloxane block copolymers”, J. Connolly, T. St Pierre, Polymer, 43, 2337 (2002), https://doi.org/10.1016/S0032-3861(02)00015-0

M. Salavati-Niasari, Z. Fereshteh, F. Davar, “Synthesis of cobalt nanoparticles from [bis (2-hydroxyacetophenato) cobalt (II)] by thermal decomposition”, Polyhedron. 28, 1065-1068 (2009). https://doi.org/10.1016/j.poly.2009.01.012

F. Teng, Z. Tian, G. Xiong, Z. Xu, “Preparation of CdS–SiO2 core-shell particles and hollow SiO2 spheres ranging from nanometers to microns in the nonionic reverse microemulsions,”, Catal Today. 93, 651 (2004). doi:10.1016/j.cattod.2004.06.125

T. Meron, Y. Rosenberg, Y. Lereah, G. Markovich, “Synthesis and assembly of high-quality cobalt ferrite nanocrystals prepared by a modified sol–gel technique”, J. Magn. Magn. Mater. 292, 11 (2005). https://doi.org/10.1016/j.jmmm.2004.10.084

Y. Ichiyanagi, S. Yamada, “The size-dependent magnetic properties of Co 3O 4 nanoparticles”, Polyhedron. 24, 2813-2816 (2005). DOI: 10.1016/j.poly.2005.03.158

Scherrer P. Bestimmung der inneren Struktur und der Gr¨oe von Kolloidteilchen mittels R¨ontgenstrahlen. Kolloidchemie Ein Lehrbuch. Springer Berlin Heidelberg, 1912.

Published
2019-08-30
How to Cite
Farahmandjou, M. (2019). Preparation of Ferromagnetic Co3O4 Nanoparticles by Wet Chemical Synthesis Method. To Physics Journal, 3, 89-99. Retrieved from http://purkh.com/index.php/tophy/article/view/468
Section
Research Articles