Characteristics of Portland Cement Pastes Blended with Silica Nanoparticles


  • Hassan Darwish National Research Centre


Cement, Nano-SiO2, Consistency, Density, Porosity, Strength


The effect of silica nanoparticles (SNP) addtion on the specific characteristics of Portland cement pastes was investigated. The results revealed that the addition of SNP to the fresh Portland cement pastes reduced both w/c ratio and setting times, but increased significantly the early age strength development. The presence of the water-reducing admixture (Na-lignosulphonate) further improved the wokability and performance of cement pastes.The replacing of SNP up to 1.5 wt. % at the expense of cemen improved and enhanced the combined water content, bulk density, total porosity and compressive strength at all curing ages of hydration. The cement mix incorporated 1.5 wt. % (Sn3) is considered to be the optimum cement patch, where it exhibited the best results and were becoming better and higher than those of the pure cement (Sn0) at all curing stages of hydration. With the addition of more than 1.5 wt. % SNP to the cement (Sn4 and Sn5), all cement properties were adversely affected. Therefore, the higher additions of NSP must be avoided.


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Author Biography

Hassan Darwish, National Research Centre

Refractories, Ceramics and Building Materials Department, Cairo, Egypt


Hewlett, PC (2004), Lea’s chemistry of cement and concrete, 5th edn, Oxford: Elsevier Science & Technology Books. ISBN : 0470 24416 X (Wiley).

Neville, AM (2011), Properties of Concrete, 5th Edn, Longman Essex (UK), ISBN: 978-0-273-75580-7 (pbk.).

Khatib, JM (2008), Performance of self-compacting concrete containing fly ash, Construction and Building Materials 2 Journal, 22, 9: 1963-1971. DOI: 10.1016/j.conbuildmat.2007.07.011.

Kuroda, M; Watanabe, T; Terashi, N (2000), Increase of bond strength at interfacial transition zone by the use of fly ash, Cem.Concr.Res., 30, 253-258.

Darweesh, HHM (2005), Effect of the combination of some pozzolanic wastes on the properties of Portland cement pastes. iiCL’industria italiana del Cemento, 808, 298-311.

Singh, NB; Middendorf, B (2008), Chemistry of blended cements part-I: natural pozzolanas, fly ashes and granulated blast furnace slags, Cem. Inter. 6, 4, 76–91.

Deschner F, Winnefeld F, Lothenbach B Seufert S, Schwesig P, Dittrich S, Goetz-Neunhoeffer F, Neubauer J (2012), Hydration of Portland cement with high replacement by siliceous fly ash, Cem. Conc. Res., 42:1389–1400.

Darweesh, HHM; Abo-El-Suoud, MR (2015), Quaternary cement composites from industrial byproducts to avoid the environmental pollution, J. EC-Chemistry, 2, 1, 78-91.

Darweesh, HHM (2017), Mortar composites based on industrial wastes, International Journal of Materials and Lifetime, Vol. 3 (1), 2017, 1-8. DOI: 10.12691/ijml-3-1-1

Darweesh, HHM (2017), Geopolymer cements from slag, fly ash and silica fume activated with sodium hydroxide and water glass, Interceram International”, 6, 1, 226-231.

Machowsk, A; Kedynskll, Z; Wilinska, I; Pacewska, B (2019), A study of the early hydration processes and properties of fly ash-slag binders, Bull. Mater. Sci., 42: 213.

Nehdi, M; Daquette, J; El-Damatty, A (2003), Performance of rice husk ash produced using a new technology as a mineral admixture in concrete, Cem. Concr. Res., 33, 1203-1210.

Chandrasekar S; Satyanarayana KG; Raghavan PN (2003), Processing, properties and applications of reactive silica from rice husk, J. Mat. Sci., 38, 3159-3168.

Abu Bakar BH; Ramadhansyah PJ; Megat MA; Johari MA (2011), Effect of rice husk ash fineness on the chemical and physical properties of concrete, Mag. Concr. Res., 63, 313-320.

Della VP; Kuhn L; Hotza D (2002), Rice husk ash as an alternative source for active silica production, Mat. Letters, 57, 818-821.

Memon SA, Shaikh MA, Akbar H (2011), Utilization of rice husk ash as a mineral admixture, Constr. Build. Mat., 25, 13, 1044-1048.

Darweesh HHM, Abo El-Suoud MR (2014), Setting, Hardening and Mechanical Properties of Some Cement / Agrowaste Composites - Part I, American Journal of Mining and Metallurgy, Vol. 2, No. 2, 32-40. DOI:10.12691/ajmm-2-2-3

Singh, NB; Singh, VD; Rai, S (2000), Hydration of bagasse ash-blended Portland cement, Cem. Concr. Res., 30, 1485-1488.

Cordeiro, GC; Toledo Filho, RD; Tavares, LM; Fairbairn, EMR (2008), Pozzolanic activity and filler effect of sugarcane bagasse ash in Portland cement and lime mortars, Cem. Concr. Comp., 30, 410–418.

Ganesan, K; Rajagopal, K; Thangavel, K (2007), Evaluation of bagasse ash as supplementary cementitious material, Cem. Concr. Comp., 29, 515-524.

Chusilp, N; Jaturapitakkul, C; Kiattikomol, K (2009), Utilization of bagasse ash as a pozzolanic material in concrete, Constr. Build. Mater., 23, 3352–3358.

Akram, T; Memon, SA; Obaid, H (2009), Production of low cost self compacting concrete using bagasse ash, Constr. Build. Mater., 23, 703–712.

Idris, MK; Eldin, K; Yassin, E (2015), Determination of the effects of bagasse ash on the properties of Portland cement, Journal of Appl. and Industr. Sci., 3 6–11.

Darweesh, HHM; Abo El-Suoud, MR (2019), Influence of sugarcane bagasse ash on Portland cement characteristics, Indian J. of Engineering, 16, 252-266. ISSN: 2319-7757

Darweesh, HHM (2007), Characteristics of metakaoline blended cement pastes” Sil. Ind. (Cer. Sci. & Techn.), Belgium, Vol. 72, Nr. (1-2), 24-32.

Khatib, JM (2008), Metakaolin concrete at a low water to binder ratio, Construction and Building Materials Journal, 22(8): 1691-1700. DOI: 10.1016/j.conbuildmat.2007.06.003.

Singh, NB; Middendorf, B (2009), Chemistry of blended cements part-II: silica fume, metakaolin, reactive ashes from agricultural wastes, inert materials and non-Portland blended cements, Cem.Inter. 6 (2009) 78–93.

Mukesh, K; Singh, SK; Singh, NP; Singh, NB (2012), Hydration of multicomponent composite cement: OPC–FA–SF–MK, Constr. Build. Mater. 36 (2012) 681–686.

El-Alfi, EA; Darweesh, HHM; El-Didamony, H (2000), Addition of limestone in the low heat Portland cement. Part I, Cer. Silikaty, Cz. Republic, 44, 3, 109-113.

Darweesh, HHM; Abo El-Anwar, A; Mekky, HS (2018), Addition of Limestone at the Expense of Gypsum in Portland Cement, Interceram International Ceramic Review, 67, 5, 18-26. DOI:

Ali, AH; Kandeel, AM; Ouda, AS (2013), Hydration Characteristics of Limestone Filled Cement Pastes, Chemistry and Materials Research, 5, 27-30

Singhand, M; Garg, M (1991), Perlite-based building materials-a review of current building materials, J. Const. & Build. Mat., 5(2):75-81.

Demirboga R; Örüng I; Gül R (2001), Effecte of expanded perlite aggregateand mineral admixtures on the compressive strength of low-density concrete”, Cem. Concr. Res., 31(11):1627-1632.

Yu LH; Ou H; Lee LL (2003), Investigation on pozzolanic effect of perlite powder in concrete, Cem. Concr. Res., 33 (1) :73-76.

Erdem TK; Meral C; Tokyay M; Erdogan TY (2007), Use of perlite as a pozzolanic addition in producing blended cements, Cem. Concr. Composites, 29:12-21.

Darweesh, HHM (2014), Utilization of Perlite Rock in Blended Cement-Part I: Physicomechanical properties, Direct Res. J. of Chemistry and Material Sciences (DRCMS), ISSN 2354-4163, Vol. 2, No. 1, 1-12.

Darweesh, HHM; Nagieb, A (2007), Hydration and micro-structure of Portland/Calcined Bentonite Blended Cement Pastes, Indian Journal of Chemical Technology, 14, 301-307.

Nalwa, HS, Ed, Handbook of Nanostructured Materials and Nanotechnology, Volumes 1-5, Academic Press, San Diego, CA (2000).

Darweesh, HHM (2018), Nanomaterials: classification and properties- Part I, Journal of Nanoscience, 1, 1, 1-11. DOI: 10.31058/j.nano.2018.11001

Alvansazyazdi M; Rosero José Augusto (2018), The Pathway of Concrete Improvement Via Nano-Technology, REVISTA INGENIO Nº 1 VOL. 2. ISSN: 2588-0829.

Darweesh, HHM (2018), Nanoceramics: Materials, Properties, Methods and Applications-Part II", Journal of Nanoscience, 1, 1, 40-66. DOI: 10.31058/j.nano.2018.11004

Sobolev, K; Ferrada-Gutiérrez, M (2005) How nanotechnology can change the concrete‖, world: Part 1, Am Ceram Soc Bull, 84 (10), pp. 14–17.

Ashby, MF; Ferreira, M F; Schodek, D L (2009) Natomaterials, nanotechnologies and design‖, ISBN: 978-0-7506-8149-0, MA 01803, USA, Linacre House, Jordan Hill, Oxford OX2 8DP, UK, Elsevier.

Morsy, MS; Alsayed, SH; Aqel, M (2010) Effect of Nano-clay on Mechanical Properties and Microstructure of Ordinary Portland CementMortar‖. International Journal of Civil & Environmental Engineering, Vol.10 No.1, pp.21-25.

ASTM–Standards (1993), Standard Test Method for Normal water of Consistency of Hydraulic Cement, C187-86: 148-150. Reapproved in ASTM Annual Book of ASTM Standards, 2008.

ASTM –Standards (1993), Standard Test Method for Setting Time of Hydraulic Cement. C191-92: 866-868. Reapproved in ASTM Annual Book of ASTM Standards, 2008.

Ren, J.; Lai, Y.; Gao, J. (2018), Exploring the influence of SiO2 and TiO2 nanoparticles on the mechanical properties of concrete, Constr. Build. Mater, 175, 277–285.

El-Didamony, H; Haggag, MY; Abo-El-Enein, SA (1978), Studies on Expansive cement : II. Hydration kinetics, surface properties and microstructure, Cem. Concr. Res., 8, 351-358.

[Kondo, R; Abo-El-Enein, SA; Diamon, M (1975), Kinetics and mechanism of hydrothermal reaction of granulated blast furnace slag, Bull. Chem. Soc. Japan, 48, 222-226.

ASTM-Standards, C 170-90 (1993), Standard test method for compressive strength of dimension stone, 828-830.

Darweesh, HHM; Abo El-Suoud, MR (2017), Saw Dust Ash Substitution for Cement Pastes-Part I, American Journal of Construction and Building Materials, 2, 1, 1-9., doi: 10.11648/j.ajcbm.20170201.11

Franke, B (1941), Determination of calcium oxide and calcium hydroxide in water free and water containing calcium silicates, Zeitschrift fur Anorganischen allgemeine Chemie, 247, 180-184.

Pressler, EE; Brunauer, S; Kantro, DL (1957), Investigation of the Franke method of determining free calcium hydroxide and free calcium oxide, Analytical Chemistry, 28, 1956, 896-902.

Javellana, M.P. and Jawed, I. (1982), Extraction of the free lime in Portland cement and clinker by Ethylene glycol, Cem. Concr. Res. 12, 3, 399-403.

Patel D.; Yadav R.K.; Chandak R. (2012), Strength characteristics of pre cast concrete blocks incorporating waste glass powder, ISCA J. Engineering Sci.,Vol.1(1), 68-70.

Khatib, JM; Hibbert, JJ (2005), Selected Engineering properties of concrete incorporating slag and metakaolin, Construction and Building Materials Journal, 19 (6): 460-472. DOI: 10.1016/j.conbuildmat.2004.07.017.

Shih JY, Chang TP, Hsiao TC (2006) Effect of nanosilica on characterization of Portland cement composite, Materials Science and Engineering: A, 424, 266-274.

Heikal M, Ali AI, Ismail MN, Awad S, Ibrahim NS (2014) Behavior of composite cement pastes containing silica nano-particles at elevated temperature, Const Build Mater, 70. 339-350.

Stefanidou M; Papayianni I (2012) Influence of nano-SiO2 on the Portland cement pastes, Compos. Part B-Eng, 43, 2706–2710.

Givi AN, Rashid SA, Aziz FNA, Salleh MAM (2010) Experimental investigation of the size effects of SiO2 nano-particles on the mechanical properties of binary blended concrete, Composites Part B: Engineering, 41, 673-677.

Nazari A, Riahi S (2011) The effects of SiO2 nanoparticles on physical and mechanical properties of high strength compacting concrete, Compos, Part B-Eng, 42, 570–578.

Aleem SAE, Heikal M, Morsi WM (2015) Hydration characteristic, thermal expansion and microstructure of cement containing nano-silica, Const Buil Mater, 59, 151-160.

Ye Q, Zhang ZN, Kong DY, Chen RS (2007) Influence of nano-SiO2 addition on properties of hardened cement paste as compared with silica fume, Constr Build Mater, 21, 3, 539–545.

Echart A, Ludwig HM, Stark J (1995) Hydration of the four main Portland cement clinker phases, Zement-Kalk-Gips, 48, 8, 443-452.

Mangi SA, Jamaluddin N, Wan Ibrahim MH, Noridah M, Sohu S (2017) Utilization of sawdust ash as cement replacement for the concrete production, A review, Engineering Science and Technology In. Research J, 1, 11-15.

Darweesh HHM (2014) Utilization of Ca-lignosulphonate prepared from black liquor waste as a cement superplasticizer, J Chemistry and Materials Research, Vol 1, No 2, 28 -34.

Darweesh HHM; Abo El-Suoud MR (2019), Palm Ash as a Pozzolanic Material for Portland Cement Pastes, To Chemistry Journal, Vol 4, 72-85. ISSN: 2581-7507.




How to Cite

Hassan Darwish. (2020). Characteristics of Portland Cement Pastes Blended with Silica Nanoparticles. To Chemistry Journal, 5, 25-39. Retrieved from



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